Atomic Layer Etching of Tungsten Disulfide Using Remote Plasma-Induced Oxidation and Wet Etching

نویسندگان

چکیده

WS 2 is an emerging semiconductor with potential applications in next-generation device architecture owing to its excellent electrical and physical properties. However, the presence of inevitable surface contaminants oxide layers limits performance -based field-effect transistors (FETs); therefore, novel methods are required restore pristine surface. In this study, thickness a layer was adjusted restored state by fabricating recessed-channel structure through combination self-limiting remote plasma oxidation KOH solution etching processes. The reaction between WO X enabled layer-by-layer control as topmost selectively removed during wet-etching process. decreased linearly number recess cycles, vertical etch rate estimated be approximately 0.65 nm cycle −1 . Micro-Raman spectroscopy high-resolution transmission electron microscopy revealed that process had nominal effect on crystallinity underlying channel. Finally, recovered removing ambient molecules from channel, which resulted high-performance FET current on/off ratio greater than 10 6 This method, provides facile approach restoring surfaces transition-metal dichalcogenide (TMDC) semiconductors precise control, has various fields such TMDC-based (opto)electronic sensor devices.

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ژورنال

عنوان ژورنال: ECS Journal of Solid State Science and Technology

سال: 2023

ISSN: ['2162-8769', '2162-8777']

DOI: https://doi.org/10.1149/2162-8777/ace6d5